Wohl, A.’s team published research in Justus Liebigs Annalen der Chemie in 440 | CAS: 14613-37-7

Wohl, A. published the artcileArecolone and N-methyl-ω-amina-β-pipecoline, Recommanded Product: (1-Methylpiperidin-3-yl)methanamine, the publication is Justus Liebigs Annalen der Chemie (1924), 139-49, database is CAplus.

Condensation of (EtO)₂CHCH₂CH₂NH₂ and HCHO gives an anhydro-base, [CH₂:NCH₂CH₂CH(OEt)₂]_n, oil which decomposes on distilling in vacuo and reduces Fehling solution and NH₄OH-AgNO₃. A modification of Blaise and Maire’s method for CH₂:CHAc (C. A. 2, 1824) is given, the yields being 25-35%. The residue, treated with AcCl, gives the compound, C₉H₁₄O₅, m. 85°. CH₂: CHAc does not appear to condense with (EtO)₂CHCH₂NH₂ to give a definite compound With (EtO)₂CHCH₂CH₂NHMe, there results the compound, (EtO)₂CHCH₂CH₂NMeCH₂CH₂Ac, light yellow oil, which cannot be distd, in vacuum but with concentrated HCl in a cooling mixture it yields 40-60% of the HCl salt, m. 204°, of arecolone (N-methyl-Δ³-tetrahydropyridine β-Me ketone), light yellow oil, b_0.01 80-2°, reduces acid KMnO₄ in the cold. HBr salt, m. 223°. Semicarbazone, m. 219° (decomposition); HCl salt, m. 233°. Arecaidine aldehyde oxime, m. 130°. Reduction with Na-Hg gives 50% of N-methyl-ω-amino-β-pipecoline, b₁₂ 116-8°; Bz derivative, m. 161-2°.

Justus Liebigs Annalen der Chemie published new progress about 14613-37-7. 14613-37-7 belongs to piperidines, auxiliary class Piperidine,Amine, name is (1-Methylpiperidin-3-yl)methanamine, and the molecular formula is C18H35NO, Recommanded Product: (1-Methylpiperidin-3-yl)methanamine.

Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem