Product Details of 177-11-7. I found the field of Chemistry very interesting. Saw the article Rhodium-Catalyzed Asymmetric Hydroamination of Allyl Amines published in 2019, Reprint Addresses Hull, KL (corresponding author), Univ Illinois, Dept Chem, 600 S Mathews, Urbana, IL 61801 USA.; Schultz, DM (corresponding author), Merck & Co Inc, Dept Proc Res & Dev, Rahway, NJ 07065 USA.; Hull, KL (corresponding author), Univ Texas Austin, 105 E 24th St, Austin, TX 78712 USA.. The CAS is 177-11-7. Through research, I have a further understanding and discovery of 1,4-Dioxa-8-azaspiro[4.5]decane.
A Rh-catalyzed enantioselective hydroamination of allylamines using a chiral BIPHEP-type ligand is reported. Enantioenriched 1,2-diamines are formed in good yields and with excellent enantioselectivities. A diverse array of nucleophiles and amine directing groups are demonstrated, including deprotectable motifs. Finally, the methodology was demonstrated toward the rapid synthesis of 2-methyl-moclobemide.
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Reference：
Piperidine – Wikipedia,
Piperidine | C5H7510N – PubChem