Wei, Peng’s team published research in Journal of Organic Chemistry in 70 | CAS: 4972-31-0

Journal of Organic Chemistry published new progress about 4972-31-0. 4972-31-0 belongs to piperidines, auxiliary class Piperidine,Benzene, name is 1-(Phenylsulfinyl)piperidine, and the molecular formula is C8H15NO, Product Details of C11H15NOS.

Wei, Peng published the artcileFactors Affecting Stereocontrol during Glycosidation of 2,3-Oxazolidinone-Protected 1-Tolylthio-N-acetyl-D-glucosamine, Product Details of C11H15NOS, the publication is Journal of Organic Chemistry (2005), 70(10), 4195-4198, database is CAplus and MEDLINE.

It is demonstrated that a ring-fused 2,3-oxazolidinone-protected derivative of 1-tolylthio-N-acetyl-D-glucosamine, e.g. β-I (R = SPhMe), undergoes high-yield stereoselective glycosidation under mild donor activation conditions to give the corresponding glycosides, e.g. I (R = OBn). Stereoselective formation of α-linked or β-linked glycosides is dependent on reactivity of acceptor alcs., where rate of glycosidation correlates to stereochem. outcome. Evidence for the role of glycosyl triflate intermediates and the N-acetyl substituent of the 2N,3O-oxazolidinone ring in stereochem. control is presented.

Journal of Organic Chemistry published new progress about 4972-31-0. 4972-31-0 belongs to piperidines, auxiliary class Piperidine,Benzene, name is 1-(Phenylsulfinyl)piperidine, and the molecular formula is C8H15NO, Product Details of C11H15NOS.

Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem