Wallace, Michael D.’s team published research in Journal of Organic Chemistry in 85 | CAS: 4972-31-0

Wallace, Michael D. published the artcileRed Algal Molecules – Synthesis of Methyl Neo-β-carrabioside and Its S-Linked Variant via Two Synthetic Routes: A Late Stage Ring Closure and Using a 3,6-Anhydro-D-galactosyl Donor, SDS of cas: 4972-31-0, the publication is Journal of Organic Chemistry (2020), 85(24), 16182-16195, database is CAplus and MEDLINE.

Me neo-β-carrabioside has been synthesized for the first time, employing either a late stage ring closure to install the required 3,6-anhydro-bridge or a suitable 3,6-anhydro-galactosyl donor to form the unfavored 1,2-cis-equatorial α-linkage. Using the late stage ring closure approach, an S-linked analog of Me neo-β-carrabioside was also realized. These compounds have applications in the identification and characterization of marine bacterial exo-α-3,6-anhydro-D-galactosidases that have specific activity on red algal neo-carrageenan oligosaccharides, such as those found in both family 127 and 129 of the glycoside hydrolases. In addition a biochem. assay using the synthesized Me neo-β-carrabioside and the marine bacterial exo-α-3,6-anhydro-D-galactosidase ZgGH129 demonstrates that the min. substrate unit for the enzyme is neo-β-carrabiose.

Journal of Organic Chemistry published new progress about 4972-31-0. 4972-31-0 belongs to piperidines, auxiliary class Piperidine,Benzene, name is 1-(Phenylsulfinyl)piperidine, and the molecular formula is C24H12, SDS of cas: 4972-31-0.

Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem