Troast, Dawn M.’s team published research in Advanced Synthesis & Catalysis in 350 | CAS: 219543-09-6

Advanced Synthesis & Catalysis published new progress about 219543-09-6. 219543-09-6 belongs to piperidines, auxiliary class Piperidine,Fluoride,Salt,Amine,Amide, name is 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate, and the molecular formula is C18H34N4O5S, Quality Control of 219543-09-6.

Troast, Dawn M. published the artcileStudies toward the synthesis of (-)-zampanolide: preparation of the macrocyclic core, Quality Control of 219543-09-6, the publication is Advanced Synthesis & Catalysis (2008), 350(11+12), 1701-1711, database is CAplus and MEDLINE.

Studies towards the synthesis of the macrocyclic core of (-)-zampanolide (I) are reported. The synthetic approach features a one-pot reduction/vinylogous aldol reaction for construction of the C-15-C-20 fragment, an intramol. silyl-modified Sakurai (ISMS) reaction for construction of the 2,6-cis-disubstituted exo-methylene pyran subunit, and use of an sp2-sp3 Stille reaction for macrocyclization.

Advanced Synthesis & Catalysis published new progress about 219543-09-6. 219543-09-6 belongs to piperidines, auxiliary class Piperidine,Fluoride,Salt,Amine,Amide, name is 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate, and the molecular formula is C18H34N4O5S, Quality Control of 219543-09-6.

Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem