Electric Literature of 5570-77-4, Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice of redox mediator can avoid electrode passivation and overpotential. 5570-77-4, Name is 4-Chloro-1-methylpiperidine, SMILES is CN1CCC(CC1)Cl, belongs to piperidines compound. In a article, author is Guyon, Helene, introduce new discover of the category.
Transition-Metal-Free Enantioselective Reactions of Organomagnesium Reagents Mediated by Chiral Ligands
Organomagnesium reagents are among the most important reagents in organic chemistry because of their great utility in forming carbon-carbon bonds. Although most enantioselective reactions using these organometallics involve transmetalation, the past decade has witnessed impressive advances in direct chiral-ligand-mediated reactions of organomagnesiums. This short review presents an overview of these achievements in enantioselective nucleophilic additions and substitutions. 1 Introduction 2 Enantioselective Nucleophilic Additions 2.1 Addition to C=O Bonds 2.2 Addition to C=N Bonds 2.3 Addition to C=C Bonds 3 Enantioselective Substitution Reactions 3.1 Sulfoxide-Magnesium Exchange 3.2 Desymmetrization via Anhydride Opening 3.3 Asymmetric Allylic Alkylation (AAA) 4 Conclusion
Electric Literature of 5570-77-4, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 5570-77-4 is helpful to your research.
Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem