Recently I am researching about N-BROMOMORPHOLINE; AMINATION; PALLADIUM; CHEMISTRY; BONDS, Saw an article supported by the NNSFCNational Natural Science Foundation of China (NSFC) [21702027, 21971034]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [2412019FZ017]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Li, Y; Ali, A; Dong, JC; Zhang, Y; Shi, LL; Liu, Q; Fu, JK. The CAS is 177-11-7. Through research, I have a further understanding and discovery of 1,4-Dioxa-8-azaspiro[4.5]decane. Recommanded Product: 1,4-Dioxa-8-azaspiro[4.5]decane
The catalytic intermolecular diamination of unactivated alkenes with electron-rich amino sources is a challenge. Herein, by employing a directing-group strategy, a copper-catalyzed diamination of unactivated alkenes was realized. Symmetrical diamines were efficiently produced in a highly diastereoselective manner with readily available dialkylamines as amino sources, while a one-pot and two-step operation was necessary to produce the unsymmetrical diamines. These reactions were proposed to proceed through aziridinium intermediates.
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Reference：
Piperidine – Wikipedia,
Piperidine | C5H7510N – PubChem