Piperidine is an organic compound with the molecular formula (CH2)5NH. This heterocyclic amine consists of a six-membered ring containing five methylene bridges (–CH2–) and one amine bridge (–NH–). 2403-88-5, formula is C9H19NO, Name is 2,2,6,6-Tetramethyl-4-piperidinol. It is a colorless liquid with an odor described as objectionable, and typical of amines. Recommanded Product: 2,2,6,6-Tetramethyl-4-piperidinol.
Li, Qianqian;Huang, Xinchen;Su, Guijin;Zheng, Minghui;Huang, Chunhua;Wang, Mengjing;Ma, Chunyan;Wei, Da research published 《 The Regular/Persistent Free Radicals and Associated Reaction Mechanism for the Degradation of 1,2,4-Trichlorobenzene over Different MnO2 Polymorphs》, the research content is summarized as follows. The role of regular/persistent free radicals on the catalytic activity of K+-tuned MnO2 tunnel structures is poorly understood to date. Herein, three MnO2 polymorphs (α-, β-, and δ-MnO2) were synthesized and examined toward the degradation of 1,2,4-trichlorobenzene (1,2,4-TrCBz) at 300 °C. δ-MnO2, with a two-dimensional-layered tunnel structure tuned by K+, exhibited the highest activity among the three MnO2 polymorphs. The ESR spectroscopy results confirmed that δ-MnO2 featured the most abundant reactive oxygen species (ROS: O2-•, •OH, and 1O2), followed by α-MnO2 (O2-• and 1O2), and β-MnO2 (O2-•), being supported by the calculated energy barrier. It was, intriguingly, noted that persistent organic free radicals, newly recognized as emerging surface-stabilized compound, were remarkably detected in α- and β-MnO2/1,2,4-TrCBz systems but not in more reactive δ-MnO2/1,2,4-TrCBz system. These might contribute to discrepant oxidative degradation process. During the oxidative process, intermediates, including benzoic acid and glycerol, formed via attack by ROS. Upon further attack, these intermediates fragmented into smaller mols. such as formic, acetic, propionic, and butyric acids. The present findings give deeper insights into the role of free radicals on the catalytic degradation of chlorinated aromatics
2403-88-5, 2,2,6,6-Tetramethyl-4-piperidinol(TEMPO) is a useful research compound. Its molecular formula is C9H19NO and its molecular weight is 157.25 g/mol. The purity is usually 95%.
TEMPO is an intermediate used in the preparation of Piperidinyloxy free radical derivatives.
TEMPO is an organic compound that acts as a radical scavenger. It is stable in the presence of water and air and can be used for the inhibition of bacterial growth. TEMPO reacts with reactive intermediates to form non-reactive substances and terminate chain reactions. This process is optimal at temperatures between 0°C and 40°C and pH values between 3.5 and 7.5. TEMPO has been shown to inhibit the growth of bacteria by reacting with reactive molecules such as amines, chlorides, or low energy radicals in aqueous solution. TEMPO also has genotoxic activity that inhibits DNA synthesis in bacterial cells through oxidation of guanine residues on DNA molecules., Recommanded Product: 2,2,6,6-Tetramethyl-4-piperidinol
Referemce:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem