Influence of experimental conditions on the electrochemical window. Case study on bis(trifluoromethylsulfonyl)imide-based ionic liquids was written by Gancarz, Pawel;Zorebski, Edward;Dzida, Marzena. And the article was included in Electrochemistry Communications in 2021.Product Details of 608140-12-1 This article mentions the following:
Ionic liquids (ILs) are often selected as electrolytes in various devices, such as batteries, capacitors and sensors, because of their chem. stability, non-flammability, low volatility, high elec. conductivity, low m.p., high thermal stability, and wide electrochem. window (EW). The width of the EW of an IL depends on the cation type, the water content, the electrode material, and the chosen specific c.d. used to measure it. In this work, the EWs of four ILs containing the common and stable bis(trifluoromethylsulfonyl)imide anion and triethylsulfonium, 1-(2-hydroxyethyl)-3-methylimidazolium, 1-methyl-1-propylpiperidinium and 1-butyl-1-methylpiperidinium cations were investigated by linear sweep voltammetry in order to analyze their electrochem. stability toward reduction and oxidation at polycrystalline platinum, gold and glassy carbon disc electrodes under anhydrous conditions. Specific current densities of 0.1 mA·cm-2 or 1 mA·cm-2 or the linear fitting method were used for the systematic comparison of the EWs obtained from each dataset. The results indicate the dependence of the EW width of each IL on the electrode material and, more importantly, on the chosen specific c.d. In this paper, we present new insight into some of the difficulties encountered during determination of the EW for ILs. In the experiment, the researchers used many compounds, for example, 1-Methyl-1-propylpiperidin-1-ium bis((trifluoromethyl)sulfonyl)amide (cas: 608140-12-1Product Details of 608140-12-1).
1-Methyl-1-propylpiperidin-1-ium bis((trifluoromethyl)sulfonyl)amide (cas: 608140-12-1) belongs to piperidine derivatives. The piperidine structural motif is present in numerous natural alkaloids. These include piperine, which gives black pepper its spicy taste. Several piperidine alkaloids isolated from natural herbs, were found to exhibit antiproliferation and antimetastatic effects on various types of cancers both in vitro and in vivo for example Piperine, Evodiamine, Matrine, Berberine and Tetrandine.Product Details of 608140-12-1
Referemce:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem