An article Copper-Catalyzed Dihydroquinolinone Synthesis from isocyanides and O-Benzoyl Hydroxylamines WOS:000461844000063 published article about C-H FUNCTIONALIZATION; ELECTROPHILIC AMINATION; MULTICOMPONENT REACTIONS; INSERTION REACTION; FACILE ACCESS; OXIMES; CYCLOADDITION; ISONITRILES; CYCLIZATION; ARYL in [Yang, Zhen; Jiang, Kun; Chen, Ying-Chun; Wei, Ye] Army Med Univ, Coll Pharm, Chongqing 400038, Peoples R China; [Wei, Ye] Southwest Univ, Sch Chem & Chem Engn, Chongqing 400715, Peoples R China in 2019, Cited 57. HPLC of Formula: C7H13NO2. The Name is 1,4-Dioxa-8-azaspiro[4.5]decane. Through research, I have a further understanding and discovery of 177-11-7
A copper-catalyzed protocol has been realized for the rapid assembly of dihydroquinolinones from readily accessible isocyanides and O-benzoyl hydroxylamines. The reactions (10 mol % of CuOAc, 10 mol % of dppe, 3 equiv of PhONa, 30 degrees C) deliver various structurally interesting dihydroquinolinones in moderate to good yields (up to 76%). The reactions may proceed in a cascade manner involving isocyanide insertion into the N-O bond, Mumm-type rearrangement, and intramolecular nucleophilic substitution.
Welcome to talk about 177-11-7, If you have any questions, you can contact Yang, Z; Jiang, K; Chen, YC; Wei, Y or send Email.. HPLC of Formula: C7H13NO2
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