Simple exploration of Methyl (R)-piperidine-2-carboxylate

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Chemistry is traditionally divided into organic and inorganic chemistry. Recommanded Product: Methyl (R)-piperidine-2-carboxylate. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent，Which mentioned a new discovery about 43041-11-8

Five-membered secondary amine heterocycles containing an alpha-heteroatom were prepared and shown to be ineffective as catalysts for the iminium ion catalysed Diels-Alder reaction between cinnamaldehyde and cyclopentadiene. Their six-membered counterparts proved to be highly active catalysts. In stark contrast, the catalytic activity observed when comparing the non alpha-heteroatom cyclic amines proline methyl ester and methyl pipecolinate showed the five-membered ring amine was significantly more active. Concurrent density functional theoretical calculations suggest a rationale for the observed trends in reactivity, highlighting that LUMO activation through an iminium ion intermediate plays a key role in catalytic activity.

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Reference：
Piperidine – Wikipedia,
Piperidine | C5H7033N – PubChem