HPLC of Formula: 175136-62-6. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Tris(3,5-bis(trifluoromethyl)phenyl)phosphine, is researched, Molecular C24H9F18P, CAS is 175136-62-6, about Platinum-Catalyzed Intramolecular Hydroalkoxylation of γ- and δ-Hydroxy Olefins to Form Cyclic Ethers. Author is Qian, Hua; Han, Xiaoqing; Widenhoefer, Ross A..
Reaction of 2,2-diphenyl-4-penten-1-ol with a catalytic mixture of [PtCl2(H2C:CH2)]2 (1 mol %) and P(4-C6H4CF3)3 (2 mol %) at 70° for 24 h led to the isolation of 2-methyl-4,4-diphenyltetrahydrofuran in 78% yield. The platinum-catalyzed hydroalkoxylation of γ-hydroxy olefins tolerated substitution at the α, β, and γ-carbon atoms and at the internal and cis and trans terminal olefinic positions. Platinum-catalyzed hydroalkoxylation tolerated a number of functional groups including pivaloate and acetate esters, amides, silyl and benzyl ethers, and pendant hydroxyl and olefinic groups. Pt-catalyzed olefin hydroalkoxylation was also applicable to the formation of fused- and spirobicyclic ethers and was effective for the hydroalkoxylation of δ-hydroxy olefins to form tetrahydropyran derivatives
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Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem