Li, Y; Ali, A; Dong, JC; Zhang, Y; Shi, LL; Liu, Q; Fu, JK in [Li, Yang; Ali, Arshad; Dong, Junchao; Zhang, Yu; Liu, Qun; Fu, Junkai] Northeast Normal Univ, Dept Chem, Jilin Prov Key Lab Organ Funct Mol Design & Synth, Changchun 130024, Peoples R China; [Shi, Lili; Fu, Junkai] Peking Univ, Shenzhen Grad Sch, State Key Lab Chem Oncogen, Shenzhen 518055, Peoples R China; [Shi, Lili; Fu, Junkai] Peking Univ, Shenzhen Grad Sch, Key Lab Chem Genom, Shenzhen 518055, Peoples R China published Copper-Catalyzed Diamination of Unactivated Alkenes With Electron-Rich Amino Sources in 2021, Cited 65. Application In Synthesis of 1,4-Dioxa-8-azaspiro[4.5]decane. The Name is 1,4-Dioxa-8-azaspiro[4.5]decane. Through research, I have a further understanding and discovery of 177-11-7.
The catalytic intermolecular diamination of unactivated alkenes with electron-rich amino sources is a challenge. Herein, by employing a directing-group strategy, a copper-catalyzed diamination of unactivated alkenes was realized. Symmetrical diamines were efficiently produced in a highly diastereoselective manner with readily available dialkylamines as amino sources, while a one-pot and two-step operation was necessary to produce the unsymmetrical diamines. These reactions were proposed to proceed through aziridinium intermediates.
Welcome to talk about 177-11-7, If you have any questions, you can contact Li, Y; Ali, A; Dong, JC; Zhang, Y; Shi, LL; Liu, Q; Fu, JK or send Email.. Application In Synthesis of 1,4-Dioxa-8-azaspiro[4.5]decane
Reference：
Piperidine – Wikipedia,
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