Pradhan, Priya P.’s team published research in Journal of Organic Chemistry in 74 | CAS: 219543-09-6

Journal of Organic Chemistry published new progress about 219543-09-6. 219543-09-6 belongs to piperidines, auxiliary class Piperidine,Fluoride,Salt,Amine,Amide, name is 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate, and the molecular formula is C11H21BF4N2O2, Synthetic Route of 219543-09-6.

Pradhan, Priya P. published the artcileOxidative Cleavage of Benzylic and Related Ethers, Using an Oxoammonium Salt, Synthetic Route of 219543-09-6, the publication is Journal of Organic Chemistry (2009), 74(24), 9524-9527, database is CAplus and MEDLINE.

Benzylic ethers and related ArCH2OR substrates are oxidatively cleaved by 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (I) in wet CH3CN at room temperature to give the corresponding aromatic aldehyde and alc. in high yield. Primary or secondary alc. products are further oxidized by I to give carboxylic acids and ketones, resp. The oxidation likely involves a formal hydride abstraction from the benzylic carbon as evidenced by slow reaction of substrates bearing electron-withdrawing substituents.

Journal of Organic Chemistry published new progress about 219543-09-6. 219543-09-6 belongs to piperidines, auxiliary class Piperidine,Fluoride,Salt,Amine,Amide, name is 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate, and the molecular formula is C11H21BF4N2O2, Synthetic Route of 219543-09-6.

Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem