Chemistry is an experimental science, COA of Formula: C10H19NO3, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 143900-44-1, Name is (S)-tert-Butyl 3-hydroxypiperidine-1-carboxylate, molecular formula is C10H19NO3, belongs to piperidines compound. In a document, author is Bhat, Muzzaffar A..
Synthesis, spectral characterization, DFT studies and biological activity of novel Ligand 1-(2-cyclohexyl thioethyl) piperidine and its complexes with group 12 metal chlorides
C-6 H11S-Na+ (generated insitu by reaction of NaOH with C6H11SH) on treatment with 1-(2-chloroethyl) piperidine hydrochloride under N-2 atmosphere resulted in (1-(2-cyclohexyl thioethyl) piperidine) (L-1) as orange solid. It’s complexes having the formula [ZnCl2. L-1] (1), [CdC1(2). (L I )] (2) and [HgC1(2). L-1] (3) have been prepared. L-1 and its complexes 1-3 were characterized on the basis of physico-chemical and spectral (FT-IR, Mass, H-1, C-13 and DEPT 135 degrees NMR) studies. Powder XRD diffraction pattern reveals the crystalline nature of L-1 and complex 1. Complexes 1-3 adopt distorted tetrahedral geometry showing bidentate mode of coordination through S and N. Using DFT-based optimization of structures, the HOMO-LUMO energy gaps and molecular electrostatic potential maps (EPM) of compound L-1 and complexes 1-3 were theoretically calculated at the B3LYP/6-311G (d, p) level of theory. HOMO-LUMO energy gap was calculated which allowed the calculation of relative properties like chemical hardness, chemical inertness, chemical potential, nucleophilicity and electrophillicity index of the synthesized products. The experimentally obtained IR and NMR results showed a good correlation with those of the theoretical ones. Ligand L-1 and complexes 1-3 display significant antibacterial and antifungal activity.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 143900-44-1, in my other articles. COA of Formula: C10H19NO3.
Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem