Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 88495-54-9, Name is (S)-1-(tert-Butoxycarbonyl)piperidine-3-carboxylic acid, molecular formula is C11H19NO4, belongs to piperidines compound, is a common compound. In a patnet, author is Zhang, Jianbo, once mentioned the new application about 88495-54-9, Safety of (S)-1-(tert-Butoxycarbonyl)piperidine-3-carboxylic acid.
Catalytic Access to Bridged Sila-N-heterocycles from Piperidines via Cascade sp(3) and sp(2) C-Si Bond Formation
Described herein is the development of an unprecedented route to bridged sila-N-heterocycles via B(C6F5)(3)-catalyzed cascade silylation of N-aryl piperidines with hydrosilanes. Mechanistic studies indicated that an outer-sphere ionic path is operative to involve three sequential catalytic steps having N-silyl piperidinium borohydride as a resting species: (i) dehydrogenation of the piperidine ring, (ii) beta-selective hydrosilylation of a resultant enamine intermediate, and (iii) intramolecular dehydrogenative sp(2) C-H silylation.
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Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem