Related Products of 79725-98-7, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 79725-98-7, Name is (4-Oxo-5-(palmitoyloxy)-4H-pyran-2-yl)methyl palmitate, SMILES is O1C(=CC(=O)C(=C1)C(=O)OCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC, belongs to piperidines compound. In a article, author is Wang, Yu-Chao, introduce new discover of the category.
Preparation of 3-hydroxyisoquinoline-1,4-dione and piperidine-2,5-dione under cerium photocatalysis from alkyne-tethered N-alkoxylamide with O-2
A facile preparation of 3-hydroxylisoquinolin-1, 4-diones and piperidine-2,5-dione from alkyne-tethered amide is reported under cerium photocatalysis and O-2 balloon. The reaction works well with a broad reaction scope and reaction efficiency. Mechanism studies indicate that 3-hydroxylpyrrolidin-2-one-containing alpha-ketol radical species serves as a possible key intermediate, and the final product is attributed to a formal N-centered radical initiated [2 + 2] cyclization and alpha-ketol rearrangement. Interestingly, divergence towards C-N bond migration and C-C bond migration is reached in this radical a-ketol rearrangement.
Related Products of 79725-98-7, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 79725-98-7.
Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem