Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 63295-48-7, is researched, SMILESS is O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.[Fe+3], Molecular C3F9FeO9S3Journal, Canadian Journal of Chemistry called Synthesis and structural studies of iron(II) and iron(III) sulfonates, Author is Haynes, John S.; Sams, John R.; Thompson, Robert C., the main research direction is iron sulfonate preparation structure; magnetic moment iron sulfonate; isomerism cobalt zinc methanesulfonate; methanesulfonate transition metal; toluenesulfonate iron; fluoromethanesulfonate iron.SDS of cas: 63295-48-7.
Fe(CF3SO3)2 and Fe(p-MeC6H4SO3)2 were prepared and on the basis of vibrational and electronic spectra and magnetic and Moessbauer data were assigned a layer lattice structure involving hexacoordinated Fe(II) and terdentate bridging anions. The FeO6 chromophore in these compounds is distorted by a trigonal elongation along the C3 axis. Fe(MeSO3)2 was obtained in 2 isomeric forms, 1 having a trigonal elongation of the FeO6 chromophore, the other a trigonal compression. No structural isomerism was found for the other Fe(II) sulfonates; however, evidence for such isomerism in methanesulfonates of Co(II) and Zn(II) is presented. While Fe(CF3SO3)2 and Fe(p-MeC6H4SO3)2 appear to be magnetically dilute, the presence of antiferromagnetic coupling in both forms of Fe(MeSO3)2 is indicated. Fe(CF3SO3)3, Fe(p-MeC6H4SO3)3, and Fe(MeSO3)3 were prepared and all 3 are magnetically concentrated exhibiting magnetic moments which are significantly less than 5.92 μB and which decrease with decreasing temperature
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Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem