Recently I am researching about ALLYLATION; LIGANDS; HYDROGENATION; REDUCTION; COMPLEXES; ENANTIO, Saw an article supported by the National Natural Science Foundation of China (NSFC)National Natural Science Foundation of China (NSFC) [21602130]; Shanghai Jiao Tong University. Product Details of 177-11-7. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Ghorai, S; Chirke, SS; Xu, WB; Chen, JF; Li, CK. The CAS is 177-11-7. Through research, I have a further understanding and discovery of 1,4-Dioxa-8-azaspiro[4.5]decane
The first earth-abundant cobalt-catalyzed highly branched- and enantioselective allylic amination of racemic branched allylic carbonates bearing alkyl groups with both aromatic and aliphatic amines has been developed. The process allows rapid access of allylic amines in high yields with exclusively branched selectivity and excellent enantioselectivities (normally 99% ee) under mild reaction conditions.
Product Details of 177-11-7. About 1,4-Dioxa-8-azaspiro[4.5]decane, If you have any questions, you can contact Ghorai, S; Chirke, SS; Xu, WB; Chen, JF; Li, CK or concate me.
Reference：
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