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Reference of 236406-39-6, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.236406-39-6, Name is 8-Boc-2,8-Diazaspiro[4.5]decane, molecular formula is C13H24N2O2. In a Article£¬once mentioned of 236406-39-6

C[sbnd]S cross-coupling catalyzed by a series of easily accessible, well defined Ni(II) complexes of the type [(NHC)Ni(Cp)(Br)]

The synthesis, characterization and catalytic evaluation of a series of NHC-Ni(II) complexes 1-Ni (-Me), 2-Ni (-nBu) and 3-Ni (-Bn) bearing a phthalimide fragment and a cyclopentadienyl (Cp) ligand is reported. The complexes were evaluated in C[sbnd]S couplings of iodobenzene and a range of thiols. The reactions were carried out using a catalyst loading of 5 mol % in DMF during 0.5?19 h. Being complex 2-Ni the one exhibiting the best activity for these transformations yielding up to 96% of products in 0.5 h.

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Reference£º
Piperidine – Wikipedia,
Piperidine | C5H19347N – PubChem