Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 179474-79-4, Name is 1-(3-Methoxypropyl)piperidin-4-amine, SMILES is COCCCN1CCC(N)CC1, in an article , author is Lee, Chang-Hee, once mentioned of 179474-79-4, Recommanded Product: 179474-79-4.
Chelation-Assisted C-H and C-C Bond Activation of Allylic Alcohols by a Rh(I) Catalyst under Microwave Irradiation
Chelation-assisted Rh(I)-catalyzed ketone synthesis from allylic alcohols and alkenes through C-H and C-C bond activations under microwave irradiation was developed. Aldimine is formed via olefin isomerization of allyl alcohol under Rh(I) catalysis and condensation with 2-amino-3-picoline, followed by continuous C-H and C-C bond activations to produce a dialkyl ketone. The addition of piperidine accelerates the reaction rate by promoting aldimine formation under microwave conditions.
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Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem