COA of Formula: C7H13NO2. Gou, Q; Liu, ZN; Cao, TW; Tan, XP; Shi, WB; Ran, M; Cheng, FX; Qn, J in [Gou, Quan; Cao, Tuanwu; Tan, Xiaoping; Shi, Wenbing; Ran, Man] Yangtze Normal Univ, Chongqing, Peoples R China; [Liu, Zining; Cheng, Feixiang] Qujing Normal Univ, Qujing, Peoples R China; [Qn, Jun] Yunnan Univ, Kunming, Yunnan, Peoples R China published Copper-Catalyzed Coupling of Sulfonamides with Alkylamines: Synthesis of (E)-N-Sulfonylformamidines in 2020, Cited 43. The Name is 1,4-Dioxa-8-azaspiro[4.5]decane. Through research, I have a further understanding and discovery of 177-11-7.
Herein, we describe an efficient copper-catalyzed coupling of sulfonamides with alkylamines to synthesize (E)-N-sulfonylformamidines. The reaction is accomplished under mild conditions without the use of a corrosive acid or base as an additive. It tolerates a broad scope of substrates and generates the products with exclusive (E)-stereoselectivity.
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Reference：
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