Recommanded Product: 1,4-Dioxa-8-azaspiro[4.5]decane. Lv, ZC; Wang, HM; Quan, ZC; Gao, Y; Lei, AW in [Lv, Zongchao; Wang, Huamin; Quan, Zhicong; Gao, Yuan; Lei, Aiwen] Wuhan Univ, Coll Chem & Mol Sci, Inst Adv Studies, Wuhan 430072, Hubei, Peoples R China; [Lei, Aiwen] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China published Dioxygen-triggered oxidative cleavage of the C-S bond towards C-N bond formation in 2019, Cited 68. The Name is 1,4-Dioxa-8-azaspiro[4.5]decane. Through research, I have a further understanding and discovery of 177-11-7.
Research on the cleavage of C-C bonds has been well developed. By comparison with this, the activation of C-S bonds remains challenging. Herein, dioxygen-triggered oxidative cleavage of C-S bonds has been achieved, delivering a series of N-containing heterocyclic compounds that are frequently found in pesticides and pharmaceuticals. Additionally, the potential utility of this protocol was further demonstrated by a gram-scale experiment. Mechanistically, dioxygen plays a key role in the cleavage of C-S bonds towards C-N bond formation.
Recommanded Product: 1,4-Dioxa-8-azaspiro[4.5]decane. About 1,4-Dioxa-8-azaspiro[4.5]decane, If you have any questions, you can contact Lv, ZC; Wang, HM; Quan, ZC; Gao, Y; Lei, AW or concate me.
Reference:
Piperidine – Wikipedia,
Piperidine | C5H7510N – PubChem