The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Tris(3,5-bis(trifluoromethyl)phenyl)phosphine, is researched, Molecular C24H9F18P, CAS is 175136-62-6, about Accessing Ambiphilic Phosphine Boronates through C-H Borylation by an Unforeseen Cationic Iridium Complex, the main research direction is ambiphilic phosphine boronate preparation crystal mol structure; cationic iridium catalyzed carbon hydrogen borylation phosphine; borane protected phosphine preparation crystal mol structure; C−H functionalization; ambiphilic molecules; borylation; homogeneous catalysis; phosphorus.Name: Tris(3,5-bis(trifluoromethyl)phenyl)phosphine.
Ambiphilic mols., which contain a Lewis base and Lewis acid, are of great interest based on their unique ability to activate small mols. Phosphine boronates are one class of these substrates that have interesting catalytic activity. Direct access to these phosphine boronates is described through the iridium-catalyzed C-H borylation of phosphines. An unconventional cationic iridium catalyst was identified as optimal for a range of phosphines, providing good yields and selectivity across a diverse class of phosphine boronates (isolated as the borane-protected phosphine). A complimentary catalyst system (quinoline-based silane ligand with [(COD)IrOMe]2) was optimal for biphenyl-based phosphines. Selective polyborylation was also shown providing bis- and tris-borylated phosphines. Deprotection of the phosphine boronate provided free ambiphilic phosphine boronates, which do not have detectable interactions between the phosphorus and boron atoms in solution or the solid state.
After consulting a lot of data, we found that this compound(175136-62-6)Name: Tris(3,5-bis(trifluoromethyl)phenyl)phosphine can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem