Chemistry is an experimental science, Quality Control of: Methyl 1-benzylpiperidine-3-carboxylate, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 50585-91-6, Name is Methyl 1-benzylpiperidine-3-carboxylate
Single crystals of [CuCl0.85Br0.15(C 6H4N3CH2=CH2)] (I) were obtained by alternating current electrochemical synthesis; their X-ray structural investigation has been carried out (DARCh automatic diffractometer, MoK alpha radiation, theta/2theta scanning; 1460 reflections with F ? 4sigma(F), R = 0.0517). The crystals are monoclinic, their space group is P21/c, a = 7.292(3) A, b = 17.947(8) A, c = 7.398(4) A, beta = 93.56(4), V = 966(1) A3, Z = 4). Complex I is close in structure to the previously investigated compound [CuCl(C6H4N3CH2=CH2)] (II). In both structures, the trigonal-pyramidal surroundings of the copper atom include two halide atoms (one is apical), a nitrogen atom, and a C=C group. The Cu2X2 dimers are associated into {[Cu2X 2(C6H5N3CH2=CH 2)]}n layers due to the bridging function of the 1-allylbenzotriazole molecule. In spite of the similar coordination polyhedra of the metal atoms and identical bridging function of the ligand molecule in I and II, the differences in the conformation parameters of the allyl group pi-coordinated by the copper(I) atom (trans-like in I and cis-like in II) caused by the presence of bromine atoms in the coordination sphere predetermine different structures of the organometallic [Cu2X2(C 6H5N3CH2=CH2)] 4 tetramer subunits in the layers and, as a consequence, formation of different crystal structures.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Quality Control of: Methyl 1-benzylpiperidine-3-carboxylate, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 50585-91-6, in my other articles.
Reference：
Piperidine – Wikipedia,
Piperidine | C5H18913N – PubChem