Sabenya, Gerard; Lazaro, Laura; Gamba, Ilaria; Martin-Diaconescu, Vlad; Andris, Erik; Weyhermuller, Thomas; Neese, Frank; Roithova, Jana; Bill, Eckhard; Lloret-Fillol, Julio; Costas, Miquel published an article about the compound: Iron(III) trifluoromethanesulfonate( cas:63295-48-7,SMILESS:O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.[Fe+3] ).HPLC of Formula: 63295-48-7. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:63295-48-7) through the article.
Iron complex [FeIII(N3)(MePy2tacn)](PF6)2 (1), containing a neutral triazacyclononane-based pentadentate ligand, and a terminally bound azide ligand has been prepared and spectroscopically and structurally characterized. Structural details, magnetic susceptibility data, and Mossbauer spectra demonstrate that 1 has a low-spin (S = 1/2) ferric center. X-ray diffraction anal. of 1 reveals remarkably short Fe-N (1.859 Å) and long FeN-N2 (1.246 Å) distances, while the FT-IR spectra show an unusually low N-N stretching frequency (2019 cm-1), suggesting that the FeN-N2 bond is particularly weak. Photolysis of 1 at 470 or 530 nm caused N2 elimination and generation of a nitrido species that on the basis of Mossbauer, magnetic susceptibility, EPR, and X-ray absorption in conjunction with d. functional theory computational analyses is formulated as [FeV(N)(MePy2tacn)]2+ (2). Results indicate that 2 is a low-spin (S = 1/2) iron(V) species, which exhibits a short Fe-N distance (1.64 Å), as deduced from extended X-ray absorption fine structure anal. Compound 2 is only stable at cryogenic (liquid N2) temperatures, and frozen solutions as well as solid samples decompose rapidly upon warming, producing N2. However, the high-valent compound could be generated in the gas phase, and its reactivity against olefins, sulfides, and substrates with weak C-H bonds studied. Compound 2 proved to be a powerful two-electron oxidant that can add the nitrido ligand to olefin and sulfide sites as well as oxidize cyclohexadiene substrates to benzene in a formal H2-transfer process. In summary, compound 2 constitutes the first case of an octahedral FeV(N) species prepared within a neutral ligand framework and adds to the few examples of FeV species that could be spectroscopically and chem. characterized.
This literature about this compound(63295-48-7)HPLC of Formula: 63295-48-7has given us a lot of inspiration, and I hope that the research on this compound(Iron(III) trifluoromethanesulfonate) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem