In an article, author is Selmani, Aymane, once mentioned the application of 477600-74-1, Name is N-Methyl-N-((3R,4R)-4-methylpiperidin-3-yl)-7H-pyrrolo[2,3-d]pyrimidin-4-amine, molecular formula is C13H19N5, molecular weight is 245.3235, MDL number is MFCD09878608, category is piperidines. Now introduce a scientific discovery about this category, COA of Formula: C13H19N5.
Construction of 1-Tetralols Bearing Two Contiguous Quaternary Chiral Centers through a Rhodium-Catalyzed Enantioselective Desymmetrization Cascade Reaction
A novel and efficient access to polyfunctionnalized chiral 1-tetralols, bearing two contiguous quaternary carbon stereocenters, has been developed from various and easily accessible alkynyl-1,3-diketones, through a cascade process including a regioselective alkyne insertion, a 1,4-Rh shift, and a nucleophilic addition step via the desymmetrization of the 1,3-diketone moiety thanks to an appropriate rhodium-chiral diene complex in the presence of arylboronic acids.
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Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem