Electric Literature of 201341-05-1, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 201341-05-1, Name is Tenofovir disoproxil, SMILES is O=C(OC(C)C)OCOP(OCOC(OC(C)C)=O)(CO[C@H](C)CN1C=NC2=C(N)N=CN=C12)=O, belongs to piperidines compound. In a article, author is Himoto, Kento, introduce new discover of the category.
Crystal structure of a new mixed-metal coordination polymer consisting of Ni-II piperidine-dithio-carbamate and pentanuclear Cu-I-I cluster units
A new heterometallic Cu-I-Ni-II coordination polymer, poly[[tetra-mu(3)-iodido-mu(2)-iodido-bis(mu(3)-piperidine-1-dithiocarbamato)propionitrilepentacopper(I)nickel(II)] chloroform monosolvate], {[(Cu5Ni5III)-Ni-I(C6H10NS2)(2)(C3H5N)]center dot CHCl3}(n), has been synthesized and structurally characterized. This coordination polymer consists of an Ni-II mononuclear unit of NiII (Pip-dtc)(2) (Pip-dtc(-) is piperidine-1-dithiocarbamate) and a pentanuclear copper(I) cluster unit of Cu5I5(CH3CH2CN). The Ni-II ion, which lies on an inversion centre, is surrounded by four S atoms in a square-planar coordination geometry while all Cu-I ions have distorted tetrahedral coordination geometries. In the pentanuclear copper(I) cluster unit, a mirror plane passes through one Cu-I ion and three I ions. All the S atoms in Ni-II (Pip-dtc) are also coordinated by the Cu-I ions, forming an infinite zigzag chain structure along the baxis direction. The chains are weakly connected by solvent CHCl3 molecules via Cl center dot center dot center dot I [3.653 (1) angstrom] and Cl center dot center dot center dot S [3.4370 (1) angstrom] short-contact interactions.
Electric Literature of 201341-05-1, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 201341-05-1 is helpful to your research.
Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem