Dmitriev, L. B. published the artcileDemyanov reaction with 1-methyl-3-aminomethylpiperidine, Safety of (1-Methylpiperidin-3-yl)methanamine, the publication is Izvestiya Timiryazevskoi Sel’skokhozyaistvennoi Akademii (1968), 195-200, database is CAplus.
A solution of 5.1 g. 1-methyl-3-aminomethylpiperidine in 50 ml. H2O was neutralized with 10% H3PO4 to pH 5.5 and a solution of 4.2 g. NaNo2 in 50 ml. H2O added dropwise at 0-5°, the mixture kept 2 hrs. at 0-5° and overnight at room temperature, heated at 70° until all gas bubbles were eliminated, and worked up to give 8% Demyanov rearrangement products I-IV, but mainly V-IX. The influence of various temperatures and pH values on the direction of the reaction was not significant.
Izvestiya Timiryazevskoi Sel’skokhozyaistvennoi Akademii published new progress about 14613-37-7. 14613-37-7 belongs to piperidines, auxiliary class Piperidine,Amine, name is (1-Methylpiperidin-3-yl)methanamine, and the molecular formula is C7H16N2, Safety of (1-Methylpiperidin-3-yl)methanamine.
Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem