Discovery of tert-Butyl 4-methylenepiperidine-1-carboxylate

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 159635-49-1, help many people in the next few years.COA of Formula: C11H19NO2

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, COA of Formula: C11H19NO2, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 159635-49-1, Name is tert-Butyl 4-methylenepiperidine-1-carboxylate, molecular formula is C11H19NO2. In a Article, authors is Zhou, Fang£¬once mentioned of 159635-49-1

NiH-Catalyzed Remote Asymmetric Hydroalkylation of Alkenes with Racemic alpha-Bromo Amides

Reported here is a terminal-selective, remote asymmetric hydroalkylation of olefins with racemic alpha-bromo amides. The reaction proceeds by NiH-catalyzed alkene isomerization and subsequent alkylation reaction, and can enantioconvergently introduce an unsymmetrical secondary alkyl group from a racemic alpha-bromo amide onto a terminal C(sp3)?H position along the hydrocarbon chain of the alkene. This mild process affords a range of structurally diverse chiral alpha-alkylalkanoic amides in excellent yields, and high regio- and enantioselectivities. In addition, the synthetic utility of this protocol is further highlighted by the regioconvergent conversion of industrial raw materials of isomeric olefin mixtures into enantioriched alpha-alkylalkanoic amides on large scale.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 159635-49-1, help many people in the next few years.COA of Formula: C11H19NO2

Reference£º
Piperidine – Wikipedia,
Piperidine | C5H13070N – PubChem