Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 827026-45-9, Name is 3-(4-Nitro-1-oxoisoindolin-2-yl)piperidine-2,6-dione, molecular formula is C13H11N3O5. In an article, author is Ito, Hajime,once mentioned of 827026-45-9, Product Details of 827026-45-9.
Copper-catalyzed asymmetric dearomative borylation: new pathway to optically active heterocyclic compounds
Chiral N-heterocyclic organoboronates represent promising intermediates for the preparation of various bioactive and pharmaceutical compounds. We recently reported the first asymmetric dearomative borylation of indoles by copper-catalyzed borylation. Then we further developed dearomatization/enantioselective borylation sequence. Chiral 3-boryl-tetrahydropyridines and chiral boryl-tetrahydroquinolines via the copper(I)-catalyzed regio-, diastereo- and enantioselective borylation of 1,2-dihydropyridines and 1,2-dihydroquinilines, which were prepared by the partial reduction of the corresponding pyridine or quinoline derivatives. This dearomatization/enantioselective borylation procedures provide a direct access to chiral piperidines and tetrahydroquinolines from readily available pyridines or quinolines in combination with the stereospecific transformation of the stereogenic C-B bond.
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Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem