Yang, Yihui; Diederich, Francois; Valentine, Joan Selverstone published the article 《Reaction of cyclohexene with iodosylbenzene catalyzed by non-porphyrin complexes of iron(III) and aluminum(III). Newly discovered products and a new mechanistic proposal》. Keywords: cyclohexene oxidation iodosylbenzene mechanism.They researched the compound: Iron(III) trifluoromethanesulfonate( cas:63295-48-7 ).Recommanded Product: 63295-48-7. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:63295-48-7) here.
Reactions of cyclohexene with iodosylbenzene (OIPh) catalyzed by non-porphyrin iron(III) and aluminum(III) complexes are reported. In addition to epoxide, other products have been observed, including cis-1,2-cyclohexanediol ditriflate, 3-acetamidocyclohexene, and 1,4-diiodobenzene. Amide oxygen in 3-acetamidocyclohexene is derived from iodosylbenzene as verified by isotopic labeling using 18OIPh. The presence of these products suggests strongly that these reactions are similar to those of iodine(III)-containing compounds which are known to react with olefins in the absence of any metal catalysts. A new mechanism is proposed which involves electrophilic attack on olefin by the iodine(III) center in a metal complex of an iodine(III)-containing ligand derived from iodosylbenzene and which accounts for all of the products.
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Reference:
Piperidine – Wikipedia,
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