Synthetic Route of 124172-53-8, Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice of redox mediator can avoid electrode passivation and overpotential. 124172-53-8, Name is N,N’-(Hexane-1,6-diyl)bis(N-(2,2,6,6-tetramethylpiperidin-4-yl)formamide), SMILES is O=CN(CCCCCCN(C1CC(C)(C)NC(C)(C)C1)C=O)C2CC(C)(C)NC(C)(C)C2, belongs to piperidines compound. In a article, author is Gan, Wenhui, introduce new discover of the category.
The reactions of chlorine dioxide with inorganic and organic compounds in water treatment: kinetics and mechanisms
Chlorine dioxide (ClO2), as an alternative to chlorine, has been widely applied in water treatment. In order to better understand the performance of ClO(2)in water treatment, the kinetics and mechanisms of ClO(2)reactions with inorganic and organic compounds found in waters are critically reviewed. In the case of inorganic compounds, ClO(2)reacts with I-, CN-, NO2-, SO32-, Fe(ii) and Mn(ii) rapidly at apparent second-order reaction rate constants (k(app)) of 10(2)-10(6)M(-1)s(-1)at pH 7.0 and barely reacts with NH(4)(+)and Br-. In the case of organic compounds, ClO(2)selectively reacts with compounds with electron-rich moieties, such as phenols (k(app)= 10(3)-10(9)M(-1)s(-1)), anilines (k(app)= 10(5)-10(8)M(-1)s(-1)), and thiols (k(app)> 10(8)M(-1)s(-1)). ClO(2)also shows high reactivity towards aliphatic tertiary amines and heterocyclic nitrogenous compounds (i.e., indoles and piperidines) withk(app)of 10(1)-10(6)M(-1)s(-1)at pH 7.0, but low reactivity with unsaturated structures (i.e., olefins and aldehydes). Thek(app)values at pH 7.0 in ClO(2)oxidation vary over 14 orders of magnitude. Electron transfer is the dominant pathway for ClO(2)reactions. Quantitative structure-activity relationships (QSARs) can be used to predict the species-specific secondary reaction rate constants for ClO(2)oxidation of compounds containing phenolic and amine structures. Little modifications are expected on the structure of the parent compounds upon the primary attack of ClO2, but further oxidation generally leads to the formation of quinones, aldehydes and carboxylic acids. Furthermore, the transformation kinetics of inorganic compounds, typical organic compounds and emerging micropollutants are compared and their half-life times under typical water treatment conditions during ClO(2)oxidation are calculated.
Synthetic Route of 124172-53-8, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 124172-53-8 is helpful to your research.
Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem