The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about S to O and O to S linkage isomerization in sulfoxide complexes of pentaammineruthenium, the main research direction is linkage isomerization kinetics ruthenium sulfoxide; ammine ruthenium DMSO linkage isomerism; aquation isomerization kinetics ruthenium DMSO; reduction potential ruthenium linkage isomer.Synthetic Route of C3F9FeO9S3.
When Ru(NH3)5(Me2SO)2+ is oxidized to the 3+ state, S → O isomerization takes place at a specific rate of (7.0 ± 0.5) × 10-2 s-1 (24 × 10-2 s-1 for the methioninesulfonate complex). Aquation is quite slow, kaq being 7.7 × 10-5 s-1 (6.2 × 10-5 s-1). On reduction to the 2+ state, O → S isomerization takes place, the values of kism being 30 ± 7 s-1 (99 ± 7 s-1). Aquation accompanies isomerization in the 2+ species and kaq ≈ 10 s-1 (30 s-1). The shift from the S- to the O-bound form changes the 3+/2+ reduction potential from 1.0 to 0.01 V.
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