Recommanded Product: 63295-48-7. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Synthesis of Cp*2Ti(OTf) and Its Reaction with Water. Author is Kessler, Monty; Hansen, Sven; Hollmann, Dirk; Klahn, Marcus; Beweries, Torsten; Spannenberg, Anke; Brueckner, Angelika; Rosenthal, Uwe.
Cp*2Ti(OTf) (2) was prepared by oxidation of the known (alkyne)titanocene complex Cp*2Ti(η2-Me3SiC2SiMe3) with Fe(OTf)3. This reaction is highly selective; formation of Cp*2Ti(OTf)2 by using an excess of the oxidizing agent was not observed Complex 2 was treated with water to give Cp*2Ti(OH)(OTf) (5) and hydrogen gas. This reaction was monitored by GC and volumetric anal. Complexes 2 and 5 were characterized by x-ray crystallog. and investigated by DFT anal.
《Synthesis of Cp*2Ti(OTf) and Its Reaction with Water》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Iron(III) trifluoromethanesulfonate)Recommanded Product: 63295-48-7.
Reference:
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