Category: 63295-48-7

Electric Literature of C3F9FeO9S3. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Crystal structure of tetrakis(tetrahydrofuran-κ O)bis(trifluoromethanesulfonato- κ O)iron(II). Author is Riemersma, Charl F.; Monkcom, Emily C.; Klein Gebbink, Robertus J. M.; Lutz, Martin.

The title compound, [Fe(CF3SO3)2(C4H8O)4], is octahedral with two trifluoromethanesulfonate ligands in trans positions and four tetrahydrofurane mols. in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystallizes in the Sohncke space group P212121 and is enantiomerically pure. The packing of the mols. is determined by weak C-H…O hydrogen bonds. The crystal studied was refined as a two-component inversion twin.

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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 63295-48-7, is researched, SMILESS is O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.[Fe+3], Molecular C3F9FeO9S3Journal, Tetrahedron called Remarkable effect of lithium salts in Friedel-Crafts acylation of 2-methoxynaphthalene catalyzed by metal triflates, Author is Kobayashi, S.; Komoto, I., the main research direction is Friedel Crafts acylation methoxynaphthalene antimony gallium triflate.COA of Formula: C3F9FeO9S3.

In the presence of a catalytic amount of a metal triflate such as Sb(OTf)3 or Ga(OTf)3, 2-methoxynaphthalene reacted with acetic anhydride in nitromethane-lithium perchlorate to afford 2-acetyl-6-methoxynaphthalene, a well-known intermediate for the synthesis of naproxen, in a high yield.

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Damavandi, Saman; Sandaroos, Reza published the article 《Solvent-free one-pot synthesis of indenoquinolinones catalyzed by iron(III) triflate》. Keywords: aminonaphthalene aminoanthracene aldehyde indandione cyclocondensation iron triflate catalyst; indenoquinolinone preparation green chem.They researched the compound: Iron(III) trifluoromethanesulfonate( cas:63295-48-7 ).Electric Literature of C3F9FeO9S3. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:63295-48-7) here.

A green three-component one-pot condensation synthesis of 16 indenoquinolinone from aromatic aldehydes, 1-aminonaphthalene or 1-aminoanthracene and 1,3-indandione catalyzed by Fe(OTf)3 was described. The isolated yields ranged from 80% to 92%.

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So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.VanAtta, Reuel B.; Franklin, Catherine C.; Valentine, Joan Selverstone researched the compound: Iron(III) trifluoromethanesulfonate( cas:63295-48-7 ).Application In Synthesis of Iron(III) trifluoromethanesulfonate.They published the article 《Oxygenation of organic substrates by iodosylbenzene catalyzed by soluble manganese, iron, cobalt, or copper salts in acetonitrile》 about this compound( cas:63295-48-7 ) in Inorganic Chemistry. Keywords: epoxidation olefin iodosylbenzene mechanism; metal nitrate triflate catalyst epoxidation. We’ll tell you more about this compound (cas:63295-48-7).

Reaction of PhIO with (Z)- (I) and (E)-stilbene (II), Me2C:CMe2 or cyclohexene in the presence of catalytic amounts of metal nitrates and triflates (metal = Fe2+, Fe3+, Mn2+, Cu2+) gave epoxidation in moderate to high yields. The same systems oxidize cumene to PhCMe2OH in moderate yields. All of the metal salt-PhIO reactions with II gave 16-86% I oxide, while reactions with I gave mixtures of II 0-82, I oxide 0-51%, and II oxide 4-51%. Some cleavage products were also observed Qual. comparisons of the epoxidation of the stilbenes catalyzed by M(O3SCF3)3 (M = Fe, Mn) with those catalyzed by the same metal porphyrins showed that the yields of the triflate- and porphyrin-catalyzed reactions were comparable for each metal ion. The triflates react more rapidly with II than with I, while the reverse was true for the porphyrins. Thus, the porphyrin ligand is not required for metal-ion catalysis of oxygenations of organic substrates by PhIO.

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Synthetic Route of C3F9FeO9S3. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Synthesis of an ionic liquid with an iron coordination cation.

An iron-based ionic liquid, Fe((OHCH2CH2)2NH)6(CF3SO3)3, was synthesized in a single-step complexation reaction. IR and Raman data suggest NH(CH2CH2OH)2 primarily coordinates to Fe(III) through alc. groups. The compound has Tg and Td values of -64° and 260°, resp. Cyclic voltammetry reveals quasi-reversible Fe(III)/Fe(ii) reduction waves.

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Synthetic Route of C3F9FeO9S3. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Fe(OTf)3- and γ-Cyclodextrin-Catalyzed Hydroamination of Alkenes with Carbazoles. Author is Xiao, En-Kai; Wu, Xian-Tao; Ma, Feng; Feng, Xiaohua; Chen, Peng; Jiang, Yi-Jun.

A Fe(OTf)3- and γ-cyclodextrin catalyzed hydroamination of alkenes with carbazoles is demonstrated. This biomimetic-catalyst-oriented sustainable and green method could deliver a wide scope of N-alkylated carbazoles and N-alkylated-carbazole-fused aromatics in up to 97% yield. The salient features of this transformation include simple and benign reaction conditions with no need for a strong base, additive, or the irradiation of light.

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Ganapathy, Hullathy Subban; Yuvaraj, Haldorai; Hwang, Ha Soo; Kim, Jong Su; Choi, Byung-Chun; Gal, Yeong-Soon; Lim, Kwon Taek published an article about the compound: Iron(III) trifluoromethanesulfonate( cas:63295-48-7,SMILESS:O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.[Fe+3] ).Recommanded Product: 63295-48-7. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:63295-48-7) through the article.

Highly CO2-soluble, conjugated polythiophenes were prepared by oxidative polymerization of 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-octyl 2-(3-thienyl)acetate (SFTE) and 2-(3-thienyl)ethyl perfluorobutyrate (FTE) with FeCl3 in supercritical carbon dioxide at 207 bar pressure and 40°. The properties of polymers, such as yield, mol. weight, elec. conductivity, and UV-vis absorption, were investigated and compared with those prepared in chloroform. The polymers showed a good solubility in CO2 at moderate pressure and temperature with higher solubility of PSFTE than PFTE.

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The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Iron(III) trifluoromethanesulfonate(SMILESS: O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.[Fe+3],cas:63295-48-7) is researched.Synthetic Route of C10H7F2N3O. The article 《The First 1,3,4-Oxadiazole Based Dinuclear Iron(II) Complexes Showing Spin Crossover Behavior with Hysteresis》 in relation to this compound, is published in European Journal of Inorganic Chemistry. Let’s take a look at the latest research on this compound (cas:63295-48-7).

Three new dinuclear complexes [FeII2(μ-L)2]X4 (L is the bis-tridentate ligand 2,5-bis{[(2-pyridylmethyl)amino]methyl}-1,3,4-oxadiazole and X = ClO4-, BF4- and CF3SO3-) were synthesized and fully characterized by single-crystal x-ray diffraction, Mossbauer spectroscopy and magnetic susceptibility measurements. Upon cooling, a trapped [high-spin-low-spin] state of the iron(II) centers was detected. Depending on the counterion, a pronounced thermal hysteresis is found. In one case, it was possible to observe a space group change that accompanies the spin transition. This is the first system showing spin crossover based on an oxadiazole ligand.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Weak Sn···I interactions in the crystal structures of the iodostannates [SnI4]2- and [SnI3]-.Computed Properties of C3F9FeO9S3.

Iodostannate complexes can be crystallized from SnI2 solutions in polar organic solvents by precipitation with large counterions. Thereby isolated anions as well as 1D, 2D, or 3D polymeric anionic substructures are established, in which SnI3- and SnI42- groups are linked by weak Sn···I interactions. Examples are the iodostannates [Me3N(CH2)2NMe3][SnI4] (I), (Ph4P)2[Sn2I6] (II), [Me3N(CH2)2NMe3][Sn2I6] (III), [Fe(DMF)6][SnI3]2 (IV), and (Pr4N)[SnI3] (V), which were characterized by single crystal x-ray diffraction. Compound I: a = 671.6(2), b = 1373.3(4), c = 2046.6(9) pm, V = 1887.7(11) × 106 pm3, space group Pbcm; II: a = 1168.05(6), b = 717.06(4), c = 3093.40(10) pm, β = 101.202(4)°, V = 2541.6(2) × 106 pm3, space group P21/n; III: a = 695.58(4), b = 1748.30(8), c = 987.12(5) pm, β = 92.789(6)°, V = 1199.00(11) × 106 pm3, space group P21/c; IV: a = 884.99(8), b = 1019.04(8), c = 1218.20(8) pm, α = 92.715(7), β = 105.826(7), γ = 98.241(7), V = 1041.7(1) × 106 pm3, space group P1̅; V: a = 912.6(2), b = 1205.1(2), c = 1885.4(3) pm, V = 2073.5(7) × 106 pm3, space group P212121.

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Name: Iron(III) trifluoromethanesulfonate. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Iron(III) trifluoromethanesulfonate, is researched, Molecular C3F9FeO9S3, CAS is 63295-48-7, about Synthesis of Conductive Polypyrrole/Polyurethane Foams via a Supercritical Fluid Process. Author is Fu, Yueping; Palo, Daniel R.; Erkey, Can; Weiss, R. A..

In the present study, we investigated the use of supercritical CO2 in the in-situ polymerization of pyrrole within a preformed polyurethane foam. The major objective was to determine the tech. feasibility of replacing organic solvents with supercritical CO2 for impregnating the oxidant into the foam and for removing the byproducts of the pyrrole polymerization reaction from the foams.

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