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Compounds of the formula (I) STR1 wherein n is a number from 1 to 20; the radicals R1 are independently of one another hydrogen, C1 -C8 alkyl, –O, –OH, –CH2 CN, C1 -C18 alkoxy, C5 -C12 cycloalkoxy, C3 -C6 alkenyl, C7 -C9 phenylalkyl which is unsubstituted or substituted on the phenyl by 1, 2 or 3 C1 -C4 alkyl; or C1 -C8 acyl; R2 has one of the meanings given for R1 ; X is C2 -C10 alkylene; and Y is –O– or >NH; with the proviso that in the individual recurrent units of the formula (I), each of the radicals R1, R2, X and Y has the same or different definitions; are very effective as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H8802N – PubChem

 

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In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 36768-62-4, name is 4-Amino-2,2,6,6-tetramethylpiperidine, introducing its new discovery. COA of Formula: C9H20N2

New double (spin and fluorescence) sensors were synthesized from aminocoumarin, pyrene and 4-nitrobenzofurazan dyes and from five- or six-membered nitroxides or their diamagnetic derivatives with aromatic nucleophylic substitution, Suzuki cross-coupling reaction and acylation reactions. The new compounds exhibit fluorescence emission between 382-529 nm affording various utilization possibilities.

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Piperidine – Wikipedia,
Piperidine | C5H8760N – PubChem

 

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A novel method for visual detection of formaldehyde with excellent selectivity via a gold(iii) complex-mediated three-component coupling reaction of resin-linked sterically bulky amines and fluorescent alkynes has been developed.

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The invention belongs to the technical field of rubber products compounding chemicals, in particular to a polymeric rubber stabilizer and its preparation method, in order to 2 – (1 ‘, 1’ – dimethyl – 3 ‘- (2’, 2 ‘, 6’, 6 ‘- tetramethyl – 4 – piperidine amino) – 1’ – ding anji) – 4 – methyl – 3 – pentene as raw material, under the effects of catalyst, high-temperature high-pressure polymerization reaction, after the reaction, cooling and rinsing, then adding activated carbon dehydration decoloring, filtering, distilling the filtrate of the invention can be prepared polymeric rubber stabilizer; the polymerized rubber stabilizer is one can inhibit or slow down because the light oxidation and make the high molecular material of the degradation of the agent, ultraviolet and excellent thermal stability, low volatility, and high molecular material has better compatibility; added to the rubber product, can improve the elasticity of the rubber, hardness, and aging-resistant performance, can also play the lubricating effect, the molecular weight is 2600 – 3400; simple synthesis process of the present invention, is low in cost and high in yield. (by machine translation)

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In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 36768-62-4, name is 4-Amino-2,2,6,6-tetramethylpiperidine, introducing its new discovery. name: 4-Amino-2,2,6,6-tetramethylpiperidine

A synthesis of N-substituted indoles by means of an epoxide-opening, nucleophilic aromatic substitution, and dehydration sequence is reported, which is capable of generating even N-tert alkyl substituted derivatives. Georg Thieme Verlag Stuttgart.

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Piperidine – Wikipedia,
Piperidine | C5H8826N – PubChem

 

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Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 36768-62-4, molcular formula is C9H20N2, introducing its new discovery. name: 4-Amino-2,2,6,6-tetramethylpiperidine

The invention relates to waxes modified with sterically hindered amines, to a process for their preparation and to their use for stabilizing organic material.

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1-Hydrocarbyloxy substituted hindered amine compounds which also contain a reactive functional group such as hydroxy, amino, oxirane or carboxyl can be chemically attached to selected polymer substrates by condensation reactions to give polymers containing a chemically-bonded, non-migrating stabilizer having excellent stabilization efficacy for protecting said polymer substrate from the adverse effects of actinic light.

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3-(1-Oxy-2,2,6,6-tetramethyl-4-piperidinyl)cyclophosphamide (7) was isolated in 36% yield following H2O2-Na2WO4 oxidation of 3-(2,2,6,6-tetramethyl-4-piperidinyl)cyclophosphamide (6), which was synthesized in three steps (25% yield) starting with 4-amino-2,2,6,6-tetramethylpiperidine. Binding of 7 to mouse liver microsomes was investigated by optical and electron spin resonance spectroscopy. Compared with the mouse liver microsomal metabolism of 1, separate incubations of 6 and an ca. 1:1 mixture of 1 and 6 gave approximately 90 and 60% less acrolein, respectively. A spin-labeled metabolite of 7, viz., N-(1-oxy-2,2,6,6-tetramethyl-4-piperidinyl)phosphoramide mustard (9), was synthesized and its intramolecular O-alkylation at pH 7.4, 37, was studied by 31P NMR spectroscopy. Compounds 7 and 9 were inactive in screening tests against L1210 lymphoid leukemia in mice.

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The spectral properties of novel pyrene-piperidine/pyrene-piperidine-1-oxyl adducts with varying linkers differing in electronic conjugation between these two functionalities were investigated in solvents of different polarity. Tuning their fluorescence efficiency via structure modification is discussed in terms of increased conjugation, solvent polarity effect, main non-radiative de-excitation pathways and static/dynamic excimer or solute-solvent exciplex fluorescence. Compared to parent pyrene molecule, the main additional non-radiative de-excitation pathways leading to significant fluorescence quenching were studied using time-resolved fluorescence spectroscopy and quantum-chemical DFT (Density Functional Theory) calculations and were identified as reductive photo-induced electron transfer and intramolecular paramagnetic quenching.

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A series of twelve novel compounds, analogues of antiviral agent MDL-860 were synthesized and their antiviral activity was evaluated in vitro against enteroviruses poliovirus 1 (PV1), Coxsackieviruses B1 (CVB1) and Coxsackieviruses B3 (CVB3). Compounds 14, 24 and 25 manifested strong antiviral effects against CVB1 and PV1 (SI values of 405 and 118 for CVB1 and PV1 respectively). In contrast to the wide anti-enteroviral activity of MDL-860, these three compounds were inactive against CVB3. Compounds 14, 24 and 25 along with MDL-860 were tested in vivo in mice infected with CVB1. Marked protective effects of compounds 14 and 24 were established, PI values of 50% and 33.3%, respectively. In addition, almost all of the tested compounds manifested very low toxicity.

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Piperidine – Wikipedia,
Piperidine | C5H8830N – PubChem