Category: 28697-11-2

A new application about 28697-11-2

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Total synthesis of (+)-homopumiliotoxin 223G

A new practical route for the first total synthesis of (+)- homopumiliotoxin 223G is described, in which the palladium-catalyzed carbonylation of the vinyl iodide, leading to efficient construction of the quinolizidine nucleus incorporating the (Z)-alkylidene side chain, is the key strategic clement. Another key feature of this synthesis involves the Lewis acid-induced chelation-controlled propargylation using the allenylsilane with complete diastereoselectivity.

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Reference£º
Piperidine – Wikipedia,
Piperidine | C5H21392N – PubChem

 

Properties and Exciting Facts About (S)-1-N-Cbz-Pipecolinic acid

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, name: (S)-1-N-Cbz-Pipecolinic acid, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 28697-11-2, Name is (S)-1-N-Cbz-Pipecolinic acid, molecular formula is C14H17NO4. In a Patent, authors is £¬once mentioned of 28697-11-2

FKBP BINDING COMPOSITION AND PHARMACEUTICAL USE THEREOF

A composition for binding FKBP proteins is disclosed, along with a method of treating conditions associated with neuronal degeneration, wherein said composition comprises a compound of Formula (I), wherein, R, R1, R2, R3 and X are as defined herein.

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Reference£º
Piperidine – Wikipedia,
Piperidine | C5H21395N – PubChem