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Three reagents are introduced for radical allylations: 3-phenylthio-2-bromopropene, 2,3-bis(trimethylstannyl)propene, and 3-tris(trimethylsilyl)silylthiopropene.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H19305N – PubChem

 

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The present invention relates to piperidines denoted by the formula: STR1 in which X is the 4-fluorobenzoyl, 2-(4-fluorophenyl)-1,3-dioxolan-2-yl or 6-fluoro-1,2-benzisoxazol-3-yl group, Y is a hydrogen atom or the hydroxyl group, m is an integer between 0 and 4 inclusive, n is 0 or 1, Q is a nitrogen atom or the methine group; when Q is a nitrogen atom, R is the cyano group or the carbamoyl group; when Q is the methine group, R is the nitro group; R1 and R2 may be identical or different and are hydrogen, a lower alkyl radical, the phenyl radical, the 2,2,2-trifluoroethyl group or the 2-[4-(4-fluorobenzoyl)-1-piperidinyl]ethyl group; or the NR1 R2 structural unit is the piperidino radical or the 4-(4-fluorobenzoyl)-1-piperidinyl group. Application of these compounds as antihypertensive medications.

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Piperidine – Wikipedia,
Piperidine | C5H19393N – PubChem

 

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Chemistry is traditionally divided into organic and inorganic chemistry. category: piperidines. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent,Which mentioned a new discovery about 236406-39-6

A free radical chain process is reported which gives vinyl sulfones or phosphine oxides in good to moderate yields under nonreducing conditions; the reaction involves irradiation of appropriate precursors to carbon-centered radicals with beta-tri-n-butylstannyl alpha,beta-unsaturated sulfones or phosphine oxides in the presence of AIBN.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H19903N – PubChem

 

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2-Aminoethyl DOTA analogues with unsubstituted (H3L 1), monomethylated (H3L2) and dimethylated (H3L3) amino groups were prepared by improved synthetic procedures. Their solid-state structures exhibit an extensive system of intramolecular hydrogen bonds, which is probably present in solution and leads to the rather high value of the last dissociation constant. The protonation sequence of H3L1 in solution corresponds to that found in the solid state. The stability constants of the H3L1 complexes with La3+ and Gd3+ (20.02 and 22.23, respectively) are similar to those of DO3A and the reduction of the pK A value of the pendant amino group from 10.51 in the free ligand to 6.06 and 5.83 in the La3+ and Gd3+ complexes, respectively, points to coordination of the amino group. It was confirmed in the solid state structure of the [Yb(L1)] complex, where disorder between the SA? and TSA? isomers was found. A similar situation is expected in solution, where a fast equilibration among the isomers hampers the unambiguous determination of the isomer ratio in solution. The PARACEST effect was observed in Eu(iii)-H3L1/H3L2 and Yb(iii)-H3L1/H3L2 complexes, being dependent on pH in the region of 4.5-7.5 and pH-independent in more alkaline solutions. The decrease of the PARACEST effect parallels with the increasing abundance of the complex protonated species, where the pendant amino group is not coordinating. Surprisingly, a small PARACEST effect was also observed in solutions of Eu(iii)/Yb(iii)-H3L3 complexes, where the pendant amino group is dimethylated. The effect is detectable in a narrow pH region, where both protonated and deprotonated complex species are present in equilibrium. The data points to the new mechanism of the PARACEST effect, where the slow coordination-decoordination of the pendant amine is coupled with the fast proton exchange between the free amino group and bulk water mediates the magnetization transfer. The pH-dependence of the effect was proved to be measurable by MRI and, thus, the complexes extend the family of pH-sensitive probes. This journal is The Royal Society of Chemistry 2013.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H19933N – PubChem

 

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Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 236406-39-6, molcular formula is C13H24N2O2, introducing its new discovery. Product Details of 236406-39-6

N-[omega-(4′-(3″-indolyl)-piperidino)-alkyl]-benzamides of the formula SPC1 Wherein R is selected from the group consisting of hydrogen and alkoxy of 1 to 3 carbon atoms, R1 and R2 are individually selected from the group consisting of hydrogen and alkyl of 1 to 3 carbon atoms, n is 2 or 3, X is selected from the group consisting of hydrogen and alkoxy of 1 to 3 carbon atoms, X1 is selected from the group consisting of hydrogen, fluorine, chlorine, bromine, –NH2 and EQU1 and X2 is selected from the group consisting of hydrogen, chlorine and sulfamoyl and their non-toxic, pharmaceutically acceptable acid addition salts having neurosedative properties and their preparation.

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Piperidine – Wikipedia,
Piperidine | C5H19637N – PubChem

 

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The present invention relates to compounds of Formula I: I which are agonists of the M-1 muscarinic receptor.

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Piperidine – Wikipedia,
Piperidine | C5H19407N – PubChem

 

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The invention relates to a chemical structural formula I indicated by the delta – amino alkyl furyl ether and in preparing the herbicide in the application: In the formula R is selected from: C1 – C2 Alkyl; n selected from: 2, 3 or 4. (by machine translation)

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Piperidine – Wikipedia,
Piperidine | C5H19479N – PubChem

 

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The present disclosure is directed to corn- pounds and methods for the treatment of disorders associated with fluid retention or salt overload, such as heart failure (in particular, congestive heart failure), chronic kidney disease, end-stage renal disease, liver disease, and peroxisome proliferator-activated receptor (PPAR) gamma agonist-induced fluid retention. The present disclosure is also directed to compounds and methods for the treatment of hypertension. The present disclosure is also directed to compounds and methods for the treatment of gastrointestinal tract disorders, including the treatment or reduction of pain associated with gastrointestinal tract disorders. The methods generally comprise administering to a mammal in need thereof a pharmaceutically effective amount of a compound, or a pharmaceutical composition comprising such a compound, that is designed to be substantially active in the gastrointestinal (GI) tract to inhibit NHE-mediated antiport of sodium ions and hydrogen ions therein. More particularly, the method comprises administering to a mammal in need thereof a pharmaceutically effective amount of a compound, or a pharmaceutical composition comprising such a compound, that inhibits NHE-3, -2 and/ or -8 mediated antiport of sodium and/or hydrogen ions in the GI tract and is designed to be substantially impermeable to the layer of epithelial cells, or more specifically the epithelium of the GI tract. As a result of the compound being substantially impermeable, it is not absorbed and is thus essentially systemically non-bioavailable, so as to limit the exposure of other internal organs (e.g., liver, heart, brain, etc.) thereto. The present disclosure is still further directed to a method wherein a mammal is administered such a compound with a fluid-absorbing polymer, such that the combination acts as described above and further provides the ability to sequester fluid and/or salt present in the GI tract

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H19454N – PubChem

 

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Imidazo[4,5-b]pyridin-2-one derivatives of the formula (I) STR1 in which n is 2, 3 or 4, x is =CH–or =N–, R 1 and R 2, which may be the same or different, each represent hydrogen, halogen or (C 1-4) alkoxy and either R 3 is H or OH and R 4 is H, or R. sub.3 and R 4 together form a direct bond, their enantiomers and their addition salts with pharmaceutically acceptable acids are pharmacologically active, for example as antagonists to histamine and serotonin.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H19681N – PubChem

 

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Layered perovskites with the formula (R-NH3)2PbI4 have excellent environmental stability but poor photovoltaic function due to the preferential orientation of the semiconducting layer parallel to the substrate and the typically insulating nature of the R-NH3+ cation. Here, we report a series of these n = 1 layered perovskites with the form (aromatic-O-linker-NH3)2PbI4 where the aromatic moiety is naphthalene, pyrene, or perylene and the linker is ethyl, propyl, or butyl. These materials achieve enhanced conductivity perpendicular to the inorganic layers due to better energy level matching between the inorganic layers and organic galleries. The enhanced conductivity and visible absorption of these materials led to a champion power conversion efficiency of 1.38%, which is the highest value reported for any n = 1 layered perovskite, and it is an order of magnitude higher efficiency than any other n = 1 layered perovskite oriented with layers parallel to the substrate. These findings demonstrate the importance of leveraging the electronic character of the organic cation to improve optoelectronic properties and thus the photovoltaic performance of these chemically stable low n layered perovskites.

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Reference:
Piperidine – Wikipedia,
Piperidine | C5H19652N – PubChem