Synthetic Route of 5799-75-7, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 5799-75-7, Name is 1-(Prop-2-yn-1-yl)piperidine, molecular formula is C8H13N. In a Article£¬once mentioned of 5799-75-7
Acetylenes as Potential Antarafacial Components in Concerted Reactions. Formation of Pyrroles from Thermolyses of Propargylamines, of a Dihydrofuran from a Propargylic Ether, and of an Ethylidenepyrrolidine from a beta-Amino Acetylene
A thermal cyclization of acetylenic compounds provides evidence for the ability of acetylenic links to act as antarafacial components in <2 + 2> processes.The cyclization competes with the normally favored acetylenic retro-ene reaction.Propargylic amines, without substituents whose presence would hinder a tight cyclic transition state, yield intermediate pyrrolines whose subsequent hydrogen elimination affords pyrroles in small amounts.The same process in 2-ethynyltetrahydropyran affords 8-oxabicyclo<3.2.1>octane in 35percent yield.A related thermal reaction of N-methyl-3-hexyn-1-amine provides a quantitative transformation to N-methyl-2-ethylidenepyrrolidine in a nominal <2s + 2a + 2s + 2s> Moebius process, wherein the acetylenic unit is the antarafacial component.Evidence for concertedness in these reactions is discussed.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Synthetic Route of 5799-75-7, you can also check out more blogs about5799-75-7
Reference£º
Piperidine – Wikipedia,
Piperidine | C5H3203N – PubChem