Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 3040-44-6, Name is 1-(2-Hydroxyethyl)piperidine, SMILES is OCCN1CCCCC1, in an article , author is Vojkovsky, Tomas, once mentioned of 3040-44-6, Product Details of 3040-44-6.
Catalytic Sulfone Upgrading Reaction with Alcohols via Ru(II)
Sulfones and sulfonamides with an a-CH bond can be easily alkylated by aliphatic alcohols to add the carbon skeleton of the alcohol via a one-step, Ru(II)-catalyzed redox neutral reaction. The reaction requires a substoichiometric amount of base and produces only water as a byproduct. Several pharmaceutically relevant functional groups such as piperidine, morpholine, etc. are well-tolerated under the reaction conditions to give higher value-added products in one step from widely available substrates. The reaction proceeds through a sulfone carbanion addition to an in-situ-generated aldehyde formed via catalytic dehydrogenation and subsequent catalyst-mediated replacement of the secondary alcohol by hydrogen.
Interested yet? Read on for other articles about 3040-44-6, you can contact me at any time and look forward to more communication. Product Details of 3040-44-6.
Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem