Bohlmann, Ferdinand’s team published research in Chemische Berichte in 97 | CAS: 13444-24-1

Chemische Berichte published new progress about 13444-24-1. 13444-24-1 belongs to piperidines, auxiliary class Piperidine,Alcohol, name is 1-Ethylpiperidin-3-ol, and the molecular formula is C7H15NO, Recommanded Product: 1-Ethylpiperidin-3-ol.

Bohlmann, Ferdinand published the artcileLupine alkaloids. XXVII. The effect of amino groups on the rate of solvolysis of esters, Recommanded Product: 1-Ethylpiperidin-3-ol, the publication is Chemische Berichte (1964), 97(6), 1619-24, database is CAplus.

cf. CA 61, 31542. The rates of solvolysis of a series of aminoalkyl azobenzenecarboxylates were investigated. The equatorial esters were always solvolyzed faster than the axial ones. The strong acceleration of the reaction by more remotely located amino and lactam groups is noteworthy. The rates of the solvolysis were determined for the azobenzenecarboxylates of the following alcs. (m.p., of ester, k × 10-3 and k × 10-4 of the hydrolysis at 19° with 0.2 and 0.02N KOH, resp., in 3:2 dioxane- H2O, and k × 10-3 and k × 10-4 of the methanolysis at 19° with 0.2 and 0.02N NaOMe in MeOH given): Me2NCH2CH2OH, 72.5°, -, 5.25, -, 9.30; iso-AmOH, 63°, -, 0.80, -, 1.40; CHC(CH2)3OH, -, -, 1.78, -, -; 6-piperidino-4-hexyn-1-ol, 60, 1.45, 1.40, -, 4.65; 6-piperidinopentanol, -, -, 0.90, -, 1.90; I, 81, 1.71, 1.12, -, 0.65; II, 106°, 1.40, 0.9, -, 1.11; III, 153°, -, 9.0, -, -; cyclohexanol, -, 0.15, -, -, 0.17; 1-methyl-4-piperidinol, -, 0.90, -, -, 1.28; 1-ethyl-3piperidinol, 69.5°, 1.83, -, -, 2.30; trans-2-dimethylaminocyclohexanol, 69°, 0.14, -, -, 0.20; 3-piperidinocyclohexanol, 124°, 0.50, -, -, 0.98; 4-dimethylaminocyclohexanol, 95-6°, 0.48, -, -, 0.98; IV, 145°, 0.73, -, 1.00, -; V, 137°, 0.042, -, 0.05, -; VI, 63°, 0.14, -, 0.013, -; VII, 110°, 0.092, -, â‰?.005, -; VIII, -, 0.74 -, 2.3, -; IX, 147°, 0.12, -, 0.2, -; X, -, 0.58, -, 0.17, -; XI, -, 0.27, -, 0.37, -; XII, -, 0.52, -, 1.8, -; XIII, 125-6°, 2.81, -, 4.4, -; XIV, 142°, 0.67, -, 0.09, -; 13a-hydroxylupinane, -, -, 0.12, -; 13a-hydroxysparteine (XV), -, -, -, 0.11, -, 17-oxo derivative of XV, -, -, -, 0.88, -; 13e-hydroxy-α-isolupinane, -, -, -, 0.77, -; 13e-hydroxy-17-oxolupinane, -, -, -, 10.0, -, 13e-hydroxylupinane, -, -, -, 1.6, -; 13e-hydroxysparteine, -, -, -, 1.5, -.

Chemische Berichte published new progress about 13444-24-1. 13444-24-1 belongs to piperidines, auxiliary class Piperidine,Alcohol, name is 1-Ethylpiperidin-3-ol, and the molecular formula is C7H15NO, Recommanded Product: 1-Ethylpiperidin-3-ol.

Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem