Bobbitt, James M.’s team published research in Journal of Organic Chemistry in 63 | CAS: 219543-09-6

Journal of Organic Chemistry published new progress about 219543-09-6. 219543-09-6 belongs to piperidines, auxiliary class Piperidine,Fluoride,Salt,Amine,Amide, name is 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate, and the molecular formula is C11H21BF4N2O2, Computed Properties of 219543-09-6.

Bobbitt, James M. published the artcileOxoammonium Salts. 6. 4-Acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium perchlorate: A stable and convenient reagent for the oxidation of alcohols. Silica gel catalysis, Computed Properties of 219543-09-6, the publication is Journal of Organic Chemistry (1998), 63(25), 9367-9374, database is CAplus.

The title piperidine-1-oxoammonium perchlorate I is a stable, nonhygroscopic oxoammonium salt that is easily prepared and can be used for the oxidation of alcs. to ketones or aldehydes in near quant. yields. The reaction is colorimetric, does not require anhydrous conditions, does not involve heavy metals, and can be carried out conveniently. Furthermore, the oxidant can be easily regenerated. The oxidation is somewhat specific in that the relative reactivities of an allyl alc. (geraniol), benzaldehyde, and 1-decanol are about 1001:0.1. The reaction is catalyzed by silica gel.

Journal of Organic Chemistry published new progress about 219543-09-6. 219543-09-6 belongs to piperidines, auxiliary class Piperidine,Fluoride,Salt,Amine,Amide, name is 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate, and the molecular formula is C11H21BF4N2O2, Computed Properties of 219543-09-6.

Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem