Aykent, Guzide published the artcileSimple Tyrosine Derivatives Act as Low Molecular Weight Organogelators, Related Products of piperidines, the publication is Scientific Reports (2019), 9(1), 1-8, database is CAplus and MEDLINE.
The gelation of L-Tyr(tBu)-OH in THF (THF) was discovered serendipitously. It was noted that this tremendously low mol. weight (LMW) compound has the ability to gel a wide variety of organic solvents (e.g., N,N-Dimetylformamide (DMF), THF, butanol, toluene), even in very low concentrations (i.e., 0.1 wt/v% in DMF). Addition of bases such as NaOH and piperidine enhanced the gel property. By changing the side-chain protecting group to tert-butyldimethylsilyl (TBDMS), a fluoride ion-responsive organogel was also acquired. This new organogelator responded fluoride ion concentration as low as 0.2 ppm. Characterization of microstructures and gel behaviors were studied by powder X-Ray diffraction spectroscopy (XRD), transmission electron microscopy (TEM), rheol. measurements and mol. dynamics (MD) simulations. Exptl. observations and theor. simulations consistently show a fiber-like structure of the gel, in which the organogelator mols. are held together via a dense network of hydrogen bonds, and via van der Waals interactions between hydrophobic groups.
Scientific Reports published new progress about 35661-58-6. 35661-58-6 belongs to piperidines, auxiliary class Piperidine,Benzene, name is 1-((9H-Fluoren-9-yl)methyl)piperidine, and the molecular formula is C19H21N, Related Products of piperidines.
Referemce:
https://en.wikipedia.org/wiki/Piperidine,
Piperidine | C5H11N – PubChem