Chemistry is traditionally divided into organic and inorganic chemistry. Quality Control of: tert-Butyl 4-(2-oxoethyl)piperidine-1-carboxylate. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 142374-19-4
Enantioselective organo-singly occupied molecular orbital catalysis: The carbo-oxidation of styrenes
The first enantioselective organocatalytic carbo-oxidation of styrenes has been accomplished using singly occupied molecular orbital (SOMO) catalysis. Geometrically constrained radical cations are generated from the one-electron oxidation of enamines formed from the condensation of aldehydes with a secondary amine catalyst. These SOMO-activated radical cations are susceptible to attack by commercially available styrenes, forming gamma-oxyaldehyde products with uniformly high levels of asymmetric induction. Broad latitude in both the aldehyde and styrene scope is readily tolerated. This report highlights the potential of SOMO catalysis to enable the development of entirely new classes of asymmetric reactions that have no traditional catalytic equivalents. Copyright
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Quality Control of: tert-Butyl 4-(2-oxoethyl)piperidine-1-carboxylate, you can also check out more blogs about142374-19-4
Reference£º
Piperidine – Wikipedia,
Piperidine | C5H18101N – PubChem