The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. HPLC of Formula: C11H20N2O3, 388077-74-5, Name is 1-Boc-2-piperidinamide, SMILES is O=C(C1N(C(OC(C)(C)C)=O)CCCC1)N, in an article , author is Du, Xinming, once mentioned of 388077-74-5.
Constructing micro-phase separation structure to improve the performance of anion-exchange membrane based on poly(aryl piperidinium) cross-linked membranes
The ether-bond-free poly(biphenyl piperidine)s are prepared to improve the alkaline stability of the anion exchange membrane (AEMs). At the same time, the construction of micro-phase separation structure is a good way to solve the trade-off’ problem between ionic conductivity and stability of AEMs. In this study, we report a new method for constructing micro-phase separation structures based on main-chain type AEMs and a crosslinking strategy that does not sacrifice ion exchange capacity. A series of poly(biphenyl piperidine)s AEMs (PAP-OH-x) are prepared by introducing 2-bromoethanol and 1,6-dibromohexane to form piperidine cationic groups and cross-linked structure. The structure of hydrophilic/hydrophobic phase separation is confirmed by TEM images. The cross-linked membrane of poly(biphenyl piperidine)s (PAP-OH-8%) membrane exhibits high conductivity of 0.081 S/cm with a rational water absorption (55.6%) and low swelling ratio (11.8%) at 80 degrees C, and also preserves the hydroxide conductivity (89.2% retention) after testing in a 5 M NaOH aqueous solution at 80 degrees C for 30 days, exhibits high alkaline stability. Furthermore, a single H-2/O-2 fuel cell with poly(biphenyl piperidine)s (PAP-OH-8%) membrane exhibits the open circuit voltage of 1.02 V and the peak power density of 290 mW/cm(2) at 60 degrees C.
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Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem