The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: tert-Butyl ((1S,2S)-2-hydroxycyclohexyl)carbamate(SMILESS: O=C(OC(C)(C)C)N[C@@H]1[C@@H](O)CCCC1,cas:145166-06-9) is researched.Computed Properties of C3H4Br2O2. The article 《Highly enantioselective direct organocatalytic α-chlorination of ketones》 in relation to this compound, is published in Angewandte Chemie, International Edition. Let’s take a look at the latest research on this compound (cas:145166-06-9).
A C2-sym. diamine I served as the organocatalyst in an asym. α-chlorination reaction of simple ketones. Optically active α-chloro ketones were formed with excellent enantioselectivities using N-chlorosuccinimide (NCS) as the chlorine source. These products have broad synthetic utility, in particular for pharmaceutical applications.
Different reactions of this compound(tert-Butyl ((1S,2S)-2-hydroxycyclohexyl)carbamate)Safety of tert-Butyl ((1S,2S)-2-hydroxycyclohexyl)carbamate require different conditions, so the reaction conditions are very important.
Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem