SDS of cas: 175136-62-6. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Tris(3,5-bis(trifluoromethyl)phenyl)phosphine, is researched, Molecular C24H9F18P, CAS is 175136-62-6, about Carbon Dioxide as a Solubility “”Switch”” for the Reversible Dissolution of Highly Fluorinated Complexes and Reagents in Organic Solvents: Application to Crystallization. Author is Jessop, Philip G.; Olmstead, Marilyn M.; Ablan, Christopher D.; Grabenauer, Megan; Sheppard, Daniel; Eckert, Charles A.; Liotta, Charles L..
Highly fluorinated organic or organometallic solid compounds can be made to dissolve in liquid hydrocarbons by the application of 20-70 bar of CO2 gas. Subsequently releasing the gas causes the compounds to precipitate or crystallize, giving quant. recovery of the solid. The resulting crystals can be of sufficient quality for single-crystal x-ray crystallog.; the structures of Rh2(O2CCF2CF2CF3)4(DMF)2, Rh2(O2C(CF2)9F)4(MeOH)2, Cr(hfacac)3, and P{C6H3(3,5-CF3)2}3 were determined from crystals grown in this manner.
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Reference:
Piperidine – Wikipedia,
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