Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 63295-48-7, is researched, SMILESS is O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.O=S(C(F)(F)F)([O-])=O.[Fe+3], Molecular C3F9FeO9S3Journal, ACS Applied Energy Materials called Photoresponsive Thermoelectric Materials Derived from Fullerene-C60 PEDOT Hybrid Polymers, Author is Zhou, Hui; Zheng, Yun; Wang, Xizu; Tan, Hui Ru; Xu, Jianwei, the main research direction is photoresponsive thermoelec derived fullerene C60 PEDOT hybrid polymer.COA of Formula: C3F9FeO9S3.
A series of fullerene-C60-PEDOT hybrid polymers HP1-7 with different contents of C60 were successfully prepared and characterized in terms of UV-vis absorption spectroscopy, thermogravimetric anal. (TGA), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Poly(3,4-ethylenedioxythiophene) (PEDOT) chains were grafted onto the surface of C60, where C60 was covalently dispersed into the whole hybrid polymer network. The thermoelec. (TE) properties of hybrid polymer films were investigated in the dark condition and under visible light irradiation In the dark condition, the HP1 (0.00 wt % C60) films showed an elec. conductivity (σ) of 240 ± 5 S cm-1 and a Seebeck coefficient (S) of 10 ± 0.6μV K-1. By increasing the C60 content in hybrid polymers, the σ gradually decreased to 70 ± 10 S cm-1 (HP7, 5.00 wt % C60). In contrast, the S rapidly increased to 19 ± 0.5μV K-1 (HP4, 1.00 wt % C60) and then reached 22 ± 1.0μV K-1 for HP7. A maximum power factor (PF) of 5.8 ± 0.2μW m-1 K-2 was achieved for HP3 films with 0.50 wt % C60. Under light irradiation, the S of HP2-4 were decreased from 13 ± 0.8, 17 ± 0.9, and 19 ± 0.5 to 9 ± 0.4, 8 ± 0.6, and 12 ± 0.4μV K-1, resp., leading to decreased PFs of 1.9 ± 0.2, 1.5 ± 0.1, and 2.4 ± 0.2μW m-1 K-2, resp. HP3 exhibited the highest light-inhibited efficiency of the TE property with its PF of approx. one-fourth of that obtained under visible light irradiation, revealing that the TE performance of these fullerene-C60-PEDOT hybrid polymers could be feasibly controlled by the irradiation of the visible light.
This compound(Iron(III) trifluoromethanesulfonate)COA of Formula: C3F9FeO9S3 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Piperidine – Wikipedia,
Piperidine | C5H11N – PubChem