Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, 14691-89-5, Name is 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl, SMILES is CC1(C)CC(NC(C)=O)CC(C)(C)N1[O], belongs to piperidines compound. In a document, author is Park, Kun Ho (Kenny), introduce the new discover, Quality Control of 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl.
A desymmetrization-based approach to morphinans: application in the total synthesis of oxycodone
Here we report a total synthesis of the pharmacologically significant morphinan alkaloid, oxycodone. The centerpiece of the developed strategy features the first application of the Rovis desymmetrization of peroxyquinol in target-oriented total synthesis to access an optically active phenanthrene framework shared by the morphinans. A Stork-Ueno radical cyclization under photoredox conditions installed the all-carbon quaternary stereocenter, and a late-stage reductive detosylation with concomitant piperidine formation secured the core structure of the target molecule.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 14691-89-5 is helpful to your research. Quality Control of 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl.
Reference:
Piperidine – Wikipedia,
,Piperidine | C5H11N – PubChem